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The Discovery of Galvanism, Electrolysis, Electrotype, and early photographic methods in printmaking from the 19th century to the present. Spencer's 1840 patent for Electro-etching. Extract from GREEN PRINTS by Cedric Green published by Ecotech Design, Sheffield, UK. - a handbook on new methods for non-toxic intaglio etching and metal plate printmaking, featuring the technique of Galv-Etch, a modern development of the 19th century electrolytic technique of Electro-Etching, and introducing Fractint and other new alternative methods avoiding the use of solvents and chemicals harmful to health and to the environment. (this section is a shortened version of "Electricity, Light and the Printed Image" a paper given at 'Jornadas de Grabado no toxico" organised by the University of Barcelona in 2004.) A SHORT HISTORY OF ELECTROLYTIC PRINTMAKING
the discovery of galvanism and electrolysis Galvanism, or chemically produced electricity, was accidentally discovered by Luigi Galvani in 1789 who was doing experiments on frog's legs and found that muscles twitched when touched by two different metals in contact, a phenomenon he attributed to a fluid in organic tissue. Soon after that Alexandre Volta showed that it was due to a direct electric current, and built a 'galvanic battery' formed by alternating zinc and copper plates separated by fabric soaked in an acidic solution (5). In 1834 Michael Faraday postulated his Laws of Electrolysis (6). Smee and Daniell invented improved versions of galvanic cells, using zinc and copper plates suspended in copper sulphate and sulphuric acid, and Thomas Spencer found that copper was deposited on the cathode or 'negative metal', and that the zinc pole was etched. He and John Wilson were granted a patent in 1840 for "Engraving Metals by Voltaic Electricity" (see Appendix B for text of patent). Spencer continued research into electro-deposition and reproduction of engraved printing plates (22). This was also utilized to reproduce seals and plate small objects by the process that became known as 'Electrotyping'. (TOP) It was found that applying a direct current from a galvanic cell to a separate 'cell' containing a couple of parallel metal plates in a metallic salt solution (the electrolyte) dissolved metal from the anode (+ve) and deposited metal on the cathode (-ve). This is explained by the fact that an electrolyte, consisting of positive and negative 'ions' will conduct a direct electrical current, which carries the ions to the plate of the opposite polarity. In a copper sulphate solution the positive copper ions collect on the negative copper plate, and negative sulphate ions react with the bare metal of the copper anode - oxidize or etch it in fact - and create new copper sulphate. Thus the electrolyte stays at the same concentration, creating the illusion that copper particles are transferred from one plate to the other - a common fallacy..(TOP) Electrotype, Electro-Etching and Galvanography The process of electrotyping become very widely used for
creating printing plates, plating metal objects, decorating silverware
and marking cutlery. In 1852 Charles V Walker documented and described
all the processes that were currently known in his book Electrotype
Manipulation, which went through 29 editions by 1859 and was
also published in the USA (7)..
Part II included detailed descriptions of Spencer and Wilson's patented
process which he called called 'Electro-Etching', and another called
'Electro-tint' (see Appendix A
for excerpts). In a series of articles in The Photographic News
in 1882, Major J Waterhouse describes "Electric Etching"
briefly. R S Chattock describes the process of electro-etching much
more fully in his book Practical Notes on Etching published in
1886 specifically for artists (8).
The word 'Galvanography' became synonymous with 'Electrotyping', basically
meaning a plate made by depositing metal over a mould, a process which
is called 'galvanoplasty', but other processes of etching or plating,
which used the same electrolytic principles and equipment were included
in the original meaning. The term 'Galvanography' was used to distinguish
the graphic use of the Electrotyping process from the industrial use or
the production of text type plates..(TOP)
electrolytic methods for printing photographs
After the invention of photography in 1839, there was international competition to find ways of making permanent ink prints of photographs, and many of the methods used electrolytic processes in one way or another. The earliest attempts, by Alfred Donne in 1839, and Joseph Berres in 1840 started with a daguerreotype, which was a photograph on a silvered copper plate, which was plated and then etched (8). But the Austrian, Paul Pretsch took a different approach and patented a process called 'photo-galvanography', in which he began with a photographically exposed dichromated-gelatine mould which was made to reticulate, from which he produced a copper intaglio plate by galvanoplasty. He formed a company in London to produce the first commercially printed photographs called "Photographic Art Treasures" in 1856 (9). .(TOP)
The French name for the Electrotype plate-making
process is 'galvanotypie' and a plate made by the process was called a
'galvano'. The process was much used in France for intaglio plate-making
in the nineteenth century, particularly by the firm of Goupil & Cie, publishers
of Fine Art reproductions. They used a process between photogravure and
Pretsch's photo-galvanography, but kept the exact process a closely guarded
secret (11). British Early
Ordnance Survey Map plates were produced by special application of galvanography.
In Sheffield, a process of thick silver plating over copper warewas developed
and called "Sheffield Plate".
the 20th century
In the
twentieth century, S W Hayter described the electrolytic process of depositing
metal into lines drawn through a ground on a metal plate, and probably
used it at Atelier17 (12).
In industry electrolytic processes were used very widely, mainly for plating
and protecting metal. Anodising was developed as a process for protecting
aluminium. In 1943 a US company called Lectroetch
adapted the Electro-Etching process to marking metals of all kinds, and
is still supplying equipment and materials for the purpose. Many other
companies have started to provide the same service, and electro-etching
became well enough known for artists who were interested to learn about
it.
In
Canada Nik Semenoff and Christine Christos carried out research into electro-etching
in 1989, and published a paper in Leonardo, an art journal in 1991, detailing
the method for artists, the equipment required, its advantages regarding
safety. (19).
In
Sweden Ole Larsen developed some electrolytic processes, and one that
he called "Polytype" was in essence the same as the "Electro-Tint"
process described by Charles V. Walker in his 1855 book (7).
(................)
For
historical and personal reasons, I prefer the original etymology, and
the prefix "galv" used in "galvanography".
I use the name 'galv-etch' , and galv-on
for applications in which the plate is etched, and for consistency, other
names using the prefix 'galv-', like galv-tone, galv-plate, or galv-type,
which will be used throughout this booklet. The names therefore can be
used freely, as can the 1850's name 'electro-etching'. .(TOP)
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